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Special Report                                                                                                                                                                   Special Report



       Reliability and effi ciency improvement in fertiliser                                                          tion of the plant. Further, revamping of  more reliable. There has been upgrada-  P O  also increased from the level of
                                                                                                                                                                                          2
                                                                                                                                                                                            5
                                                                                                                     civil structures to improve longevity of  tion in the instrumentation system from  93% in 1992-93 to 98% at present.
       plants                                                                                                        the plants are being carried out.  PLC-based to  DCS-based. Use of ad-  The water consumption of ammonia
                                                                                                                                                       vance process control systems further
                                                                                                                        In sulphuric acid plants, opera-  help in optimisation of the parameters  and urea plants has been reduced by
            ertiliser production involves   higher mass fl ow. A number of plants  detection systems for reactors are avail-  tional challenges have been overcome  and smooth operation of the plant.  about  50%,  while  complex  fertiliser
            employment  of very sophisti-  have implemented this scheme in pro-  able from some technology providers.   by improving conversion efficiency  Technologies like artifi cial intelligence  plants have been able to reduce water
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       Fcated  technologies and process-  cess air, carbon dioxide and synthesis  Use of such a system during operation   and improvement in waste heat  and machine learning are now  being  consumption by 60% over last 26 years.
       ing, handling and storage of hazardous   gas compressors. Ammonia plants were  may help in attending to the very small   recovery.              adopted to predict the problems in ad-  The  wastewater  discharge  has  been
       chemicals like sulphur, ammonia, sul-  revamped for higher conversion by in-  defects before they become severe and        ChemImpex            vance. Electrical systems are also made  drastically  brought down during the
                                                                                                                                                                                IndiaChemTrade
       phuric acid, nitric acid, phosphoric acid   corporating additional converter. Further,  affect  reliability  of  the  plant.  There   Complex fertiliser plants are highly  more reliable by improving the power  same period.
       and other hazardous chemicals. Plants   effi ciency  has  been  improved  by  re-  have been developments in materials of   dependent  on imported raw materials  factor, transformer, other electrical
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       also operate under extreme condition of   vamping  the compressors, turbines  construction (MoC) of stripper, such as   and intermediates for production. Raw  systems and grid synchronisation.  The  survey  report  for  downtime
                                                                                                                      ChemImpex, the trade database, tracks, on a daily
       temperature  and pressure. Any break-  or  replacing  them  with  more  effi cient  bimetallic or proprietary materials that   materials  account for major  part of   IndiaChemTrade provides consolidated trade statistics
                                                                                                                                                                                         shows  that forced shutdown due to
                                                                                                                      basis, exports and imports of chemicals and related
                                                                                                                                                                       of India. The information provided here is based on the
       down  of the plant can lead to heavy   ones.                       offer  better corrosion  resistance. Life   overall  cost  of  production.  Therefore,  Improvements in effi ciency and   equipment problems in ammonia plants
                                                                                                                      products through the major ports in India — a vital
       losses on account of energy and produc-                            of the existing strippers were improved    improvement in raw material use effi -  reliability  annual trade data published by the Directorate General
                                                                                                                                                                                         reduced  from  average  of  24.4  down-
                                                                                                                                                                       of Commercial Intelligence and Statistics, Government
                                                                                                                      source of commercial intelligence. Find out on-line
       tion. Reliability of plant and machinery   Urea production         by reversal of stripper after a few years   ciency is of utmost importance. For   These efforts have resulted in signi-  time in days per plant per year (DDPY)
                                                                                                                      how international markets are moving; where your
                                                                                                                                                                       of India. The database can be searched by: Chemical
       is very important for continuous opera-  Urea plants have been modifi ed to  of operation and shortening of stripper   improving  the  operational  effi ciency,  fi cant  improvement  in  effi ciency  and  in 1987-1990 to 6.1 DDPY in 2020-23.
                                                                                                                                                                       Name/Harmonised Code to obtain the consolidated
                                                                                                                      competitors are exporting and at what price; where
       tion, effi ciency and safety of the plants.   improve  the  conversion  effi ciency  of  and save capital investment  in a new   efforts have been made to improve the  reliability  of  fertiliser  plants.  The  The  urea  plants  also  reduced  forced
       This assume more signifi cance in view   reactor by installing additional trays or  equipment.                 recovery  effi ciency  of  ammonia  and  Fertiliser Association of India (FAI) is  shutdowns due to equipment problems
                                                                                                                      imports are coming from and how their prices are
                                                                                                                                                                       trade (import or export) in that item; or by Country to
       of the fact that vintage of most of the   replacing old trays with improved de-                               phosphoric acid. These plants have  monitoring vital parameters of effi ciency  from 11.8 DDPY to 6.1 DDPY during
                                                                                                                      moving. Download all this data, seamlessly, for a
                                                                                                                                                                       obtain the trade (import or export) in all chemicals and
       urea and complex fertiliser  plants in   sign ones. A few plants have installed a  Production of complex fertilisers  undertaken  modifi cations  in  granulator  and environment for the  last several  the corresponding period.
                                                                                                                      small fee — online, anytime, with no hassles.
                                                                                                                                                                       related products between India and that country
       India is in the range of 20 to 50 years   vortex mixer in the reactor to increase   Production of NP/NPK complex   and pipe reactor systems for precise  years. Efforts of the industry are refl ec-
       with exception of six urea plants com-  the  conversion  effi ciency  and  reduce  fertilisers involves reactions of sul-  control of grade formulation. Modifi ed  ted in very signifi cant improvement in   There  has  been  continuous  em-
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       missioned during 2019 to 2022. Being   steam consumption. Urea plants have  phuric acid with rock phosphate to pro-  design of scrubbing system has resulted  performance of all fertiliser plants.  ployment of  new  technologies, timely
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       energy- and capital-intensive, effi cient   been revamped  with additional  stages  duce phosphoric acid  and then reac-  in reduced ammonia and particulate                       replacement  of  old  and  ineffi cient
                                                                                                                      ChemXchange — the chemical exchange with a difference — is where you can identify your buyers and sup-
       and reliable operations also play a key   such as pre-decomposer and pre-  tion of ammonia with phosphoric acid   matter losses from stack, besides pro-  The  energy  consumption  for  the  equipment, adoption of high degree of
                                                                                                                      plyers on-line, any time. This unique platform is free to all advertisers in the print version of Chemical Weekly.
       role in ensuring viability of the plants.  concentrator  for higher raw materials  to produce complex fertilisers. Due   viding  operational  fl exibility  to  the  ammonia plants has been reduced from  automation, better maintenance prac-
                                         recovery  and  savings  in  steam.  There  to  acidic nature of materials  handled,   plant.                  12.48-Gcal/tonne  in  1987-88  to  8.07-  tices  leading  to  improved  effi ciency,
       Ammonia production                have been efforts to improve the quality  these plants are also prone to corrosion          For more information contact: 022-24044477. Fax: 022-24044450
                                                                                                                                                       Gcal/tonne  ammonia  in  2022-23  and  reliability, safety, and environmental
                                                                                                                                 Email: corporate@chemicalweekly.com or log on to chemicalweekly.com
          Ammonia is the key intermediate   of fertiliser  products. Plants have in-  and erosion of material. The equipment   More reliable and safe operations  for urea plants from 8.87-Gcal/tonne to  performance of the plants.
       for production of nitrogenous fertilisers.   stalled acoustic system, vibro-priller or  needing special attention in  sulphuric   Technological  advancement  in  the  5.71-Gcal/tonne during the same period.
       The  ammonia  production  processes   specially designed prill buckets to im-  acid plant are reactor, intermediate and   fi eld  of  instrumentation  and  control  In case of complex fertiliser plants, the   [Indian Journal of Fertilisers, 20 (6):
       involve reactions that are both endo-  prove the quality of the prills as well as  fi nal absorption and drying towers. The   have made plant operations safer and  raw material effi ciency of Nitrogen and   534-535, June 2024]
       thermic and exothermic in nature.   reduce dust emissions.         critical  equipment in phosphoric acid
       Effi ciency of the process depends upon                             plants are digester, fl ash cooler, recycle
       utilisation  of the  endothermic heat   Corrosion is one of the critical fac-  acid tank, scrubber and vacuum cooler.
       supplied by burning of fossil fuels and   tors affecting the reliability  of equip-  These  equipments  are  lined  with  spe-
       waste heat from fl ue gases and exother-  ment in urea plant due to handling of  cial and  rubber  materials to improve
       mic reactions. Ammonia plants are   corrosive materials such as ammonium  corrosion resistance.                                                    Missed a copy !!!
       effectively utilising these heats to gene-  carbamate, an  intermediate compound
       rate either steam or preheat process gas   produced during the making of urea.   Units making complex  fertilisers         For Digital Edition of this month’s issue & all other past issues
       or air. Older heat exchangers have been   Precautions such as maintaining passi-  have optimised the process for various
       replaced with newer improved designed   vation air and use of special materials  grades  of products  and  to  withstand                Visit www.hpicindia.com
       heat exch angers for higher heat transfer   for reactors, strippers, decomposers,  corrosive environment  by changing
       and waste heat recovery. The low-level   pipelines, etc., which come in contact  to improved materials  of construction
       heat, which was earlier wasted in cool-  with carbamate solution susceptible to  (MoCs)  for equipment, and mainte-                          PDF copies available for download
       ing water, is used in vapour absorption   corrosion are being undertaken. Repair  nance practices to achieve higher pro-                               Register Now
       machines  (VAM) to cool the process   and maintenance procedures and work-  ductivity.  As  result of aging, timely                                       Mrs. Usha S. - usha@hpicindia.com
       gas for compression thus increasing its   manship are critical  for  ensuring reli-  replacement  of  a  vessel/equipment is   Contact: For Subscription   : Mrs. Usha S. - usha@hpicindia.com
       effi ciency and also the capacity due to   ability of these equipment. Online leak  important  for safe and reliable  opera-                  For Advertising   : Mr. Vijay Raghavan - vijay@hpicindia.com
       174                                                                      Chemical Weekly  July 16, 2024       Chemical Weekly  July 16, 2024                                                                  175
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