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Special Report


          80ºC is critical temperature for the  and  9)  the  ease  of  maintenance  and   Consulting Resources Corporation,
          evolution of atomic hydrogen.  overhaul.                           Houston, (2004).
           Care should be taken that the  re-                                 Hileman,  B.,  Long,  J.R.,  and
          verse potential does not go over 0.82 V,    Internal stresses generated by   Kirschner, E.M., Chemical Engineer-
          which is the evolution potential of  cold work, welding, fabrication, and   ing News, Vol. 21, (Nov. 21, 1994).
          hydrogen  on  titanium.  Figure-23  installation can cause SCC. Proper    Mantell,  C.L.,  Electrochemical  Engi-

          depicts polarization current flowing  maintenance of plant and proper pro-  neering, 4th Edition, McGraw-Hill Book
          from cathode to anode during plant  cedure followed during shutdown   Company, Inc., New York, (1960).
          shutdown, causing reverse potential  will also go in a long way to reduce     MacMullin,  Electrolysis  of Brines

          up to 1.5 V (above hydrogen evolu-  corrosion.                     in Mercury Cells, Ed. Sconce, J.S.,
          tion potential).                                                   Chlorine: Its  manufacture, proper-
           As the transients and peaks for Ti-  Weld zones are structurally and   ties, and uses, R.E.Kreiger Publish-
          6Al-4V-ELI  increases  at  a  higher  compositionally different from the bulk   ing Company, New York, (1978).
          (basic) pH, cells should be drained  metal and may suffer localized corro-      Chlorine Institute, North American
          immediately after shutdown to pre-  sion. Sudden changes in operating pres-  Chlor-Alkali Plants,  Pamphlet #
          vent migration of the caustic from  sure  and  flow  velocity  may  generate   10, Chlor-Alkali Producers outside
          cathodic side to the anodic side.  erosion corrosion, impingement attack,   North  America, Pamphlet  # 16,
                                 2+
           As higher concentration of Ca  and  and crevice  corrosion.  Non-uniform   New York, (1976).
          Mg  ions accelerate corrosion, the  heat transfer can lead to the formation    Bertram, B.M., Sodium Chloride,
            2+

          quality of brine in the clarifier and ion  of scale, causing local increases in tem-  Kirk-Othmer Encyclopedia of Chemi-
          exchange column should be lowered.  perature and corrosion. Use of dissimilar   cal  Technology,  4th  edition,  Vol.23,
           Iron surface contamination  should  metals can cause galvanic corrosion. Di-  John Wiley & Sons, Inc. (1997).
          be avoided at temperature > 77 C.  rect contact between such metals should    Coin,  R.J.,  Brine  Treatment,  16th
                                    o

          Ti surface  may be cleaned  by   be avoided by design of by insertion of   Annual Electrode Corporation,
          immersing  it  in  35%  HNO   –  5%   insulators. However, the insulating ma-  Chlorine/chlorate Industry Seminar,
                                3
          HF solution  for 2-5 minutes   terials, gaskets, and seals may lead to   Cleveland, (2000).
          followed by a water rinse.     crevice  corrosion.  Leakage  of  air  may    Davis, W.H., Open Cell-Room Ope-

                                         accelerate general corrosion of carbon   rations, 24th Chlorine Institute Plant
          Considering the above factors res-  steel,  while  dissolved  oxygen  benefits   Operations Seminar, Houston, (1981).
       ponsible for corrosion in chlor-alkali  stainless steels by passivating surfaces.      Fontena, M.G., Process Industries
       industry operations, the suitable mate-                               Corrosion, National Association of Cor-
       rials of construction issummarised  in  REFERENCES                    rosion Engineers, Houston, (1975).
       Table-5. (15, 16 and 17).             Brien, S., ‘Paper presented at the 1999    Wranglen,  G.,  An Introduction to

                                           World Petrochemical Conference’,    Corrosion and Protection  of Met-
       CONCLUSIONS                         Houston, TX, March 24-25, (1999).  als, Institute of Metallskydd, Stock-
          The  corrosion  resistance  aspects    The global chlor-alkali  industry –   holm, (1972).

       for different material of construction   strategic implications and impacts:    Herbert, R.W., Selection of  Appro-

       in chlor-alkali industry have been dis-  Final Report,  Volume IV/Product   priate Materials of Construction in
       cussed in detail and the recommended   Trees, SRI International  Multi-   Chlor-Alkali Plants, 4th Annual Elec-
       construction materials has been listed.   Client Project # 2437, (1993).  trode Corporation-Chlorine/chlorate
       But other design and fabrication con-      Hale,  A.J.,  ‘The  Applications  of   Seminar, Chardon, Ohio, (1987).
       siderations must also be considered for   Electrolysis in Chemical Industry’,    Krishnamurty, S., Muthukumar-

       preventing corrosion in chlor-alkali   Longmans Green & Co., New York,   swamy, S.,  Thangappa, R., Chlor-
       industry.  These include: 1) residual    pp: 90-100, (1918).          Alkali Plants Materials  of Con-
       stresses in the structure, 2) heat     Schultze, H.W., Jeffery, T.C., Danna,    struction, editor: Mcketta, J.J., and

       affected  zones  near  welds,  3)  proper   P.A., and Holden, H.S., Chlorine Bi-  Cunningham, W.A., Encyclopaedia
       geometry for fluid flow, 4) structure of   centennial Symposium, The Electro-  of Chemical Engineering & Design,
       the heat transfer unit and its surface,   chemical Society, Princeton (1974).  Marcel Dekker, New York, (1987).
       5) use of dissimilar metals, 6) gaskets    Peterson, R., Chlorine, Caustic,    Grove, D.E., Modern Chlor-Alkali


       and seals, 7) air leakage, 8) fluctuation   and Derivatives: Insights and Out-  Technology, Vol.3,  Ellis  Horwood,
       in pressure, temperature, and flow rate,   look,  Chlor-Alkali  Summit,  2004,   Chichester, (1986).

       196                                                                  Chemical Weekly  December 3, 2024


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