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Special Report                                                                                                                                                                   Special Report



       Global LNG markets heading towards supply glut;                                                               Stress corrosion cracking in buried pipelines with a

       likely to benefi t India’s gas offtake: ICRA                                                                   case example

             fter two volatile years in terms   120                       key challenge, given the falling share of
             of natural gas supplies and pric-  100                       the APM gas in the overall gas mix.        INTRODUCTION                      stress and a corrosive medium. Metal or   DR. S.K. CHAKRAVORTY
       Aing in CY2022 and CY2023,         80                                                                              tress corrosion cracking (SCC)  alloy is virtually unattacked over most   Consultant (Plant Engineering)
       the global liquifi ed natural gas (LNG)   60                           The fertiliser segment will remain           is often the predominant failure  of its surface, while fi ne cracks progress   Email: chakravorty4410@gmail.com
       markets are now heading towards signi-  40                         the largest off-taker of natural gas, albeit   Sin high-pressure gas transmis-  through it (Figure-1). After processing
       fi cant  supply  glut  with  large  capa-  20                       the demand from hereon is not expect-      sion pipelines. Long-term operation  only a few batches, many  cracks ap-
       city additions planned from CY2024 to   0                          ed to grow, given there are no further     of pipelines could lead to degradation  peared on the outside surface of a high-
                                                      Q1FY2025
       CY2028. Globally, about ~193-mt of   FY2021 FY2022 FY2023 FY2024  FY2025E FY2026E FY2027E  capacity expansions in the urea segment.  of mechanical  properties of the steel,  pressure autoclave forged from 18-8 SS
       the  LNG production  and liquefaction                                                                         including  a  signifi cant  reduction  of  with 2-in. wall. The surface was cooled   Tensile  Susceptible
       capacity is slated to be added over the   Fig. 1: Trend in natural gas production in   Marginal growth in gas production  brittle fracture resistance and resistance  by water and the cooling-water-jacket   Stress  material
       course of the next four years. Signi-       india, mmscmd             Going forward, domestic gas pro-        to  SCC.  The  impact  toughness of oil  system was drained after each  opera-     SCC
       fi cant capacity addition amid expectation   prices and  an uptick in the domestic  duction will witness  marginal growth   and gas pipeline steels, and the SCC  tion.  The droplets of  water clinging
       of modest demand growth in the global   gas production.            over the course of FY2025 and FY2026       resistance of pipeline steels, important  to the autoclave surface dried and the
       natural gas consumption will keep the                              with  the ramp  up of production  from     for structural  integrity, are  often  not  chloride present in water concentrated
       LNG  prices  under  check,  benefi tting   This  growth is supported  by the  ONGC’s KG-98/2 basin in Q4 FY2025   regulated and given due consideration.  causing SCC.                        Corrosive
       India.                            City Gas  distribution (CGD)  sector,  and on-streaming of few stranded gas                                                                               environment
                                         followed by the refi neries’ offtake. The  production fi elds.                   SCC begins when small  cracks     Not all metal-environment  combi-
          Speaking on this, Girishkumar Kadam,   demand from the CGD sector is under-                                develop on the external  surface of  nations are susceptible  to cracking.
       Senior  Vice President and  Group   pinned by the CNG  segment, which   Given the expectation of a growth     buried pipelines. In severe cases, it can  Stainless steels crack in chloride   Conditions necessary for SCC occur
       Head, Corporate Ratings, ICRA Ltd.,   remains  robust owing to the  strong  of 6-8% YoY in natural gas consump-  end in structural failure. SCC is a type of  and caustic environments, but not in
       said: “Global natural gas consumption   economic advantage over  alternate  tion in the country, the reliance on LNG   environmentally assisted cracking (EAC),  ammonia,  whereas brasses crack in   Fig. 2: Conditions necessary for occurrence
                                                                                                                                                                                                      of SCC
       is expected to witness modest growth,   fuels, following the strong uptick in  will, however, remain material.  The   caused by various factors combined  ammonia-containing environments, but
       given the focus of the major natural   CNG vehicle  sales in the last couple  share of LNG  in the gas mix is pro-  with the environment surrounding the  not in chlorides.       are referred to as “the environment.”
       gas consumers in regions of Euro-  of years.  The increasing  adoption  jected to increase from 48% in FY2024   pipeline. It occurs by a combination if                           This environment may be isolated
       pean Union, Japan & Korea towards   of electric  vehicles  in the passenger  to 50% in FY2025. However, since   corrosion and tensile stress. Corrosion   The  important variables affecting  from the surrounding soil by the pipe
       other  sources  of energy. Amidst  these   vehicle and bus segments will remain  domestic production is expected to start   is related to susceptibility of the material  stress corrosion cracking are tempera-  coating, and the conditions at the pipe
       demand headwinds, the LNG capacity   key threats for the CNG offtake. Addi-  moderating from FY2028 onwards, the   to the environment, while stresses may  ture, Solution composition, metal com-  surface may be different from those in
       addition over the next four year, which   tionally, ability of the CGD entities to  reliance  on LNG would further rise   be residual, external or operational  position, stress, and metal  structure.  the surrounding soil.
       is equivalent  to ~41% of the current   ensure availability of CNG at competi-  as India looks to increase the share of   (1, 2, & 3).          Cracking is accelerated  by increasing
       global LNG  production capacity, is   tive prices going forward will remain a  natural gas in the energy mix.                                   temperature. Most  susceptible  alloys   The four factors controlling the for-
                                                                                                                                                                             o
       expected to result in a downward pressure                                                                     What is SCC                       will begin cracking at 100 C. The pre-  mation of  the potent environment for
       on the global  LNG prices.  India  thus   250  56%                                         60%                   SCC refers to cracking caused by  sence of dissolved oxygen or other oxi-  the initiation of SCC are the type and
       stands  to  benefi t  in  terms  of  availabi-   49%         48%   52%   50%   49%   49%                       the simultaneous presence of tensile  dizing agents is critical to the cracking  condition of the coating, soil, tempera-
       lity of LNG at reasonable prices over   200           44%                                  50%                                                  of austenitic  SS in chloride  solutions  ture and cathodic protection  current
       the medium term, notwithstanding the                                                       40%                                                  and removal of oxygen will prevent the  levels.
       near-term volatility amid geo-political   150                                              30%                                                  attack.
       tensions in West Asia.”             100                                                                                                                                              SCC often begins on the pipeline
                                                                                                  20%                                                  Conditions that lead to SCC       surface at areas where coating disbond-
       Recovery in gas consumption          50                                                    10%                                                     The occurrence of SCC depends on  ment or  coating  damage occurs.  The
          India’s gas consumption, after wit-                                                                                                          the simultaneous achievement of three  ability of  a coating to resist disbond-
       nessing headwinds in FY2023 owing     0                                                    0%                                                   conditions: a potent cracking environ-  ment is a primary performance pro-
       to the elevated LNG prices, recovered   FY2021  FY2022  FY2023  FY2024 Q1FY2025  FY2025E  FY2026E  FY2027E                                      ment; a material  susceptible to SCC;  perty of coatings and affects all forms
       sharply to 187.9-mmscmd in FY2024                                                                                                               and a tensile stress higher than thresh-  of external pipeline corrosion. Coatings
       (~17% increase  YoY) with easing of                  LNG Consumption                                                                            old stress (Figure-2)(3).         with good adhesion properties are gene-
       LNG prices. Consumption in India                     Domestic gas consumption                                                                                                     rally resistant to the mechanical action
       is expected  to  grow by 6-8% YoY in                 % Share of LNG in consumption-RHS                         Fig. 1: Stress corrosion of type 304 stainless   A potent cracking environment  of soils from wet/dry cycles and freeze/
       FY2025, supported by softer LNG            Fig. 2: Trend in domestic and LNG consumption in India, mmscmd                steel autoclave           The conditions at the pipe surface  thaw cycles. They also are better able to

       182                                                                Chemical Weekly  September 10, 2024        Chemical Weekly  September 10, 2024                                                             183


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