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 IOC selects cumene technology from Lummus

 for phenol project


 Lummus  Technology, a global   Phenol manufacturing process  increasing  popularity  of  the  ethylene   Paraformaldehyde    Spain
 provider of process technologies and   The classical process for phenol –  route for methyl methacrylate (MMA) –
 value-driven energy solutions, has   accounting for most of all phenol  an important end-use for acetone now –
 announced that Indian Oil Corporation   produced worldwide – is based on  instead of the traditional acetone
 Ltd. (IOC) has selected the Lummus/  cumene and involves the co-production  cyanohydrin route, could pose a
 Versalis cumene technology for a 440-  of acetone. The process starts with  threat to future acetone growth and   91-92-93-96% Prills
 ktpa unit in Paradip, Odisha. The new   reacting benzene and propylene to yield  consumption.
 cumene unit is part of a grassroots petro-  cumene, which is then converted into
 chemical and polymers expansion at   cumene hydroperoxide (CHP) by   In India, phenol mainly serves as one
 IOC’s complex in Paradip.  oxidation in air. In the second step of the  of two raw materials for production of PF
 process, purifi ed CHP is split to yield  resins, which fi nd use as adhesive, parti-
 “Our cumene technology will offer   phenol and acetone in equimolar pro-  cularly in the plywood industry. There
 Indian Oil lower energy costs, reliabi-  portion, producing  about  0.61-tonnes  are other relatively smaller end-uses for
 lity, operational effi ciency and excep-  of acetone for every tonne of phenol.  phenol as well, including for making
 tional product  yield,  which will  help   foundry resins, alkylphenols and several
 them optimise their plant economics   The economics of this ‘2 for 1’  fi ne chemicals. Phenol’s high exposure
 and support their growth initiatives,”   process  benefi ts  from  the  twin  revenue  to the PF resins market in India – to the
 said Mr. Romain Lemoine, Chief Busi-  streams it affords and is usually a  extent of about 60% of total demand –
 ness  Offi cer  for  Polymers  and  Petro-  factor in its favour. But balancing the  sets it apart from elsewhere in the world,
 chemicals, Lummus Technology. “We   markets for the two products can also  wherein BPA represents half of global   Pentaerythritol 98%   Spain
 look forward to continue working   be a challenge. Phenol and acetone  phenol demand, and PF resins represent
 with Indian Oil on another successful   serve very different markets – except  only a quarter.
 project and building on our long-time   for bisphenol  A (BPA) manufacture
 relationship.”  (which requires both) – and acetone   Demand for phenol in India has tradi-
 demand is more diverse than for phenol.  tionally been growing around GDP
 Lummus’ scope includes the tech-  In the recent past, most plants have  levels – averaging a CAGR of about
 nology license for the cumene techno-  been built primarily for the phenol  7%. Between 2019-20 and 2021-22,
 logy, basic design engineering, proprie-  needed to make derivatives including  growth fell sharply – to about 4%
 tary catalyst, site services, advisory   BPA, phenol-formaldehyde (PF)  annually – due to Covid but has since
 services, and training.  resins, intermediates for nylons, alkyl-  recovered to the trendline growth.
 phenols, etc.
 IOC  has licensed  multiple  Lummus   The acetone market presents a more
 technologies, including naphtha cracker,   Phenol & acetone markets  complex picture. Historical growth   Sodium Formate 97%  Spain
 INDMAX FCC and polypropylene   The main driver of phenol demand  rates have been lower than for phenol,
 technologies at complexes across   globally (though not in India) is BPA,  at a CAGR of 4%.  Again,  COVID
 India.  which demand, in turn, is driven by  took a toll, with demand decline seen
 two important end-uses: polycarbonate  in 2020-21 and virtually no growth in   Contact Sole  Agent
 Lummus and  Versalis have part-  (PC) and epoxy resins (in order of  the ensuing year. The prognosis for the
 nered to license cumene technologies   importance). Growth rates for acetone,  near-term is better, but only slightly so.  FLUORODYECHEM
 since 2007. The cumene process is a   typically used as a solvent, have tended
 liquid-phase alkylation technology   to lag phenol, in part because important   India  remains  a  signifi cant  importer   A-311/312, Kanara Business Centre, Laxmi Nagar, Ghatkopar (E), Mumbai-400 075.
 using a proprietary zeolite catalyst and is   end-use segments for acetone, such as  of both phenol and acetone, and   Tel: 022-25001958/25000348/67988454 w Fax: 022-25000464/21716029
 characterised by a very high cumene   coatings, are seeing a switch to water-  several of their derivatives. Imports   Email:dyechem777@gmail.com
 yield, ultra-high purity cumene pro-  based systems on grounds of environ-  in FY23 were around 400-kt (phenol)
 duct and a long catalyst run length.  mental friendliness. Furthermore, the  and 210-kt (acetone.  Liason Offices at : KOLKATA and SOUTH INDIA


 130  Chemical Weekly  May 7, 2024  Chemical Weekly  May 7, 2024                                       131


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