Page 134 - CW E-Magazine (21-1-2025)
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Point of View
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          This feedstock was first leveraged by the crackers in the Middle East to serve global markets, and later in the US, where the shale gas boom
       resulted in an upsurge in ethane availability. Petrochemical producers elsewhere jealously eyed their cost advantage but could do little to benefit.   5-Ethyl-2-Methylpyridine  Calcium Lactate Gluconate  Guanidine Nitrate
       That is now changing. Ethane exports from the US are rising and going to countries in North America (Canada), Latin America, Europe, as well as   AAEMA  Calcium Malate         Hexahydrophthalic Anhydride
       China, India and Japan in Asia. RIL was amongst the early ones to tie in ethane supplies from the US and has an efficient supply chain, including   Ammonium Acetate  Calcium Nitrate  Hydrobromic Acid 48%
       six Very Large Ethane Carriers (VLECs), to ferry the feedstock to the West Coast of India. In Europe, INEOS has taken a similar route to overcome
       the serious feedstock disadvantage the European petrochemical industry is grappling with. It now feeds its cracker in Grangemouth (Scotland)   Ammonium Adipate  Calcium Oxalate  Hydroxyacetone
       with imported ethane, bettering its competitiveness over others cracking liquids.                                  Ammonium Citrate                Calcium Phosphate            Magnesium Acetate
                                                                                                                          Ammonium Formate                Calcium Phospholactate       Malononitrile
          Closer home, Gail India Ltd. and ONGC have signed a tripartite agreement with Shell Energy India Pvt. Ltd. to explore opportunities for the import   Ammonium Lactate  Calcium Propionate  Methyl Nadic Anhydride
       of ethane and other hydrocarbons at Shell’s import terminal at Hazira. Gail operates two 450-ktpa crackers at Pata, in Uttar Pradesh, which can   Ammonium Oxalate  Calcium Saccharate  N-Hexene
       use ethane or propane, and is building a 1.2-mtpa ethane-fed cracker near its 5-mtpa liquefied natural gas (LNG) plant at Dabhol (Maharashtra). In   Ammonium Tartrate  Calcium Stearate  N-Valeroyl Chloride
       addition, just a couple of weeks ago Nayara Energy (the erstwhile Essar Oil), announced that it too is considering an ethane-cracker.
                                                                                                                          Benzonitrile                    Calcium Sulfate              O-Cyclohexylphenol
          India’s ethane imports are estimated to have touched about 2.0-mt in 2023, but with a few more petrochemical players looking to go this   Calcium Acetate  Calcium Tartrate  Ortho Chlorobenzonitrile
       route to olefins, imports will rise.                                                                               Calcium Bisglycinate            Crotonic Acid                Para Chlorobenzonitrile
                                                                                                                          Calcium Carbonate               Cyanuric Chloride            Paraldehyde
       Coal and MTO                                                                                                       Calcium Chloride                Cyclohexene                  P-Cymene
          The deployment of MTO/CTO technologies has been only in China. From the first plants built using imported MTO technology around 2010,   Calcium Citrate  DETDA               Phenothiazine
       the scale up has been dramatic. Today, most of China’s MTO plants are based in the developed eastern coast (using imported methanol), while   Calcium Citrate Malate  Diisopropyl Ether  Piperazine Anhydrous
       the CTO plants are located mainly in the coal-producing northern and northwestern parts. The dominant technology in use is the one developed
       by the Dalian Institute of Chemical Physics.                                                                       Calcium Copper EDTA             Dimethyl Acetyl Succinate    Potassium Bicarbonate
                                                                                                                          Calcium Disodium EDTA           Dimethyl Succinylo Succinate  Potassium Carbonate
          But CTO plants face two major challenges. The first is the availability of water, especially in the coal-belt where most are located. The second   Calcium Formate  Ferric Ammonium Citrate  Potassium Hydroxide
       relates to the heavy carbon footprint that comes with using coal. So far the latter has not mattered, but in a future where some carbon penalty   Calcium Fumarate  Ferric Ammonium Oxalate  Tertiary Butyl Alcohol
       (such as a carbon tax) is levied, CTO plants could be handicapped severely compared to steam crackers running on naphtha as feedstock.  Calcium Gluconate  Ferric Ammonium Sulfate  Thiophenol
                                                                                                                          Calcium Glycerophosphate        Ferrous Ammonium Sulfate     Triacetin
       Ethanol for ethylene                                                                                               Calcium Hydroxide               Guanidine Carbonate          Valeronitrile
          In Brazil, PE is now produced from ethylene derived from ethanol and marketed to niche & discerning markets with better margins as a
       ‘green’ polymer. In India, India Glycols Ltd. (IGL) produces ‘green’ MEG from bioethanol-derived ethylene that it sells to make a partly bio-based
       polyethylene terephthalate (PET) resin (the terephthalic acid still comes from petroleum), which PET bottle Coca-Cola uses for its eponymous   PLEASE CONTACT WITH YOUR SPECIFIC REQUIREMENTS
       drinks in some select markets. Fully renewable-carbon based ethoxylates, used as surfactants, are on offer from speciality chemicals company,
       Clariant.                                                                                                                                               CHEMET

          But all said and done, ethylene production from bioethanol is still a niche.

       Crude oil to chemicals – the future?                                                                               HEAD OFFICE : Span Centre, 2nd Floor, Ramakrishana Mission Road, Santacruz(West), Mumbai - 400 054, INDIA.
          Several refining and petrochemical companies are now turning their attention to the direct conversion of Crude-Oil-To-Chemicals (COTC), in   Tel : +91-22-66802222 / 26045601 E-Mail : info@chemetindia.com Website: www.chemetindia.com
       preparation for a world wherein fuel production could become less attractive. COTC is particularly attractive for high-growth regions – such as
       China, India, and the Middle East – that have traditionally been reliant on integrated refining-petrochemical plants.                                  BRANCH OFFICES
                                                                                                                          AHMEDABAD OFFICE : 1101, Safal Prelude,      HYDERABAD OFFICE : Flat No. 104, K1 Primo,
          But the challenge with COTC is economics. Due high investment costs, capital efficiency will be critical in determining profitability and those   Corporate Road, Nr.Prahladnagar Garden,   Kondapur X Roads, Hanuman Nagar, Kondapur,
       companies and countries with significant construction efficiencies will be prime candidates for COTC. But since a large amount of chemicals is   Anandnagar, Ahmedabad - 380 015, INDIA.
       produced for each project, having accessible markets will be a major consideration. Technology is yet another competitive factor. COTCs are more                Hyderabad-500 084, Telangana, INDIA.
       complex to operate, so choosing the best process configuration and technologies is key.                            Tel :  +91-79-40370725                       Tel : +91-40-4856 5970 / 71
                                                                                                                          E-Mail : chemetahmedabad@chemetindia.com
                                                                                                                                                                       E-Mail : chemethyderabad@chemetindia.com
          China has already demonstrated the value of the aromatics variant of COTC with several complexes commissioned recently, which support   NEW DELHI OFFICE : 214, Hans Bhavan,
       the Chinese polyester value chain. In India, RIL has stated its intent to ramp up the chemicals conversion of its existing refineries at Jamnagar.   Wing No.1, Bahadurshah Zafer Marg,   KOLKATA OFFICE : Sharma House, 3rd Floor, 1/2, Lord
       In the Middle East, oil/petrochemical majors are eyeing COTC projects, which will deploy some novel technologies and harness existing ones in   New  Delhi - 110 002, INDIA.  Sinha Road, Kolkata - 700 071, INDIA.
       complex operations.
                                                                                                                          Tel : +91-11-45751865                        Tel : +91-33-22827247 / 22826511
          A massive shift from refining to petrochemicals could result in over-investment into petrochemicals, with the risk that this would erode   E-Mail : chemetdelhi@chemetindia.com   E-Mail : chemetkolkata@chemetindia.com
       petrochemicals margins in the future.                                                                              CHENNAI OFFICE : 8-J, Century Plaza, 560-562,
                                                                                                                          Anna Salai, Teynampet, Chennai - 600 018, INDIA.
          The diversity in feedstock options for olefins production will stay, but their relative weightage will continue to evolve.
                                                                                                                          Tel : +91-44-24342245 / 24349301
                                                                                              Ravi Raghavan               E-Mail : chemetchennai@chemetindia.com


       134                                                                   Chemical Weekly  January 21, 2025


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