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Special Report



       Coal gasifi cation in India – the unfi nished story

             oal  gasifi cation  as  we  know  since  2006.  There  were  few  who  lis-  D.M. MOHUNTA
             today and touted as great pana-  tened and most enamoured with natural
       Ccea has been practiced in large  gas, pooh-poohed the idea.        Commercial, Chemical and
                                                                           Development Company
       scale  since  1936  in  Germany.  The                               E-mail:dmm@ccdcindia.com
       purpose was to use the gas produced as  Development of technology
       fuel  for  industry  and  households,  and   One must go back many decades to   An important reason for adoption of
       many hundred kilometres of gas pipe-  understand  the  development  of  gasifi -  coal gasifi cation is that it is a relatively
       lines were laid in Europe. By 1946, coal  cation technology.       clean  technology,  with  lower  pollution
       gasifi cation  was  recognised  as  an  im-                         and higher thermal effi ciency compared
       portant source of syngas (synthesis gas –   Gasifi cation  of  coal  has  been  to other coal-burning technologies.
       a  mixture  of  carbon  monoxide  and  known for more than century and half
       hydrogen)  for  chemical  production  in  in  some  industrial  form  or  another.   An  study  from  Department  of
       USA and Germany. Very detailed work  It  was  messy  and  there  was  pollu-  Energy  (DoE),  USA,  indicates  that
       was done on all aspects of gasifi cation  tion load. It lost priority with advent  even  if  it  is  used  for  power  generation
       of coke and lignite under widely diffe-  of  plentiful  natural  gas  and  LPG.  gasifi cation  is  superior  in  terms  of
       ring operating conditions.        There were sporadic developments in  thermal  effi ciency  and  pollution  load.
                                         the  USA  and  Germany  on  gasifying  Coal-based  Integrated  Gasifi cation
          This author has been advocating not  coal  to  produce  gases  that  could  be  Combined  Cycle  (IGCC)  plants  have
       only coal gasifi cation, but gasifi cation  converted  to  industrial  products  like  thermal  effi ciencies  of  50-55%,  com-
       of heavy tar and other low value fuels  those derived from petroleum.  pared to 40-50% for the best coal-based



                                    REFINERIES                OPERATIONS                    DME

                                                              METHANOL
                                                                                         FORMALDEHYDE

                                    CHEMICALS                 AMMONIA
                                                                                          MTBE
                                                              OXOCHEMICALS:
                                                                 BUTANOL,
                                    SYNTHETIC NATURAL                                    ACETIC ACID
                                        GAS(SNG)              ETHYLHEXANOL


                     SYNGAS         DIRECT REDUCTION                                       AMINE
         GASIFICATION                   IRON (DRI)
                     (H +CO)
                       2                                                                 POLYPROPYLENE
                                                         TOWN GAS
                                    GAS INDUSTRY       O /N /H /CO/AR
                                                        2  2  2
                                                                                         GASOLINE, LPG
                                    GAS TO LIQUID
                                                                                          UREA

                                     TO OLEFINES                                         AMMONIA NITRATE
                                                                                            /SULFATE
                                    HEAT & POWER
                                        IGDC
                                      Fig. 1: Products that can be made by coal gasifi cation


       Chemical Weekly  April 30, 2024                                                                 193


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