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Special Report                                                                   Special Report



 More of white hydrogen  Norway, Ukraine, Russian Federation  been reported to be aware of the poten-  Department  of Energy has announced
       and Kazakhstan. Launched in 2014, the  tial of white hydrogen in India. (Hindu  the  establishment a $20-mn fund to
       well in Bourakebougou, Western Mali,  Business Line, Jan 20, 2023). Is it not  help  companies  and  researchers  fi nd
 ydrogen is a colourless invisi-  But not much attention has gone into   A.K. DAS  remains the world’s only exploited  high time for planning to exploit  this  low-cost and sustainable  ways to ex-
 ble gas,  but over the years a  this direction as explorations were   Retd. Industrial Adviser  white hydrogen site till now. The pro-  clean energy source?  tract underground hydrogen. It has been
 Hcolour code has been attached  being conducted mostly to fi nd minerals   Department of Chemicals & Petro-  duction, reported  to be only around   recently reported that several start-ups
 to hydrogen.  The ‘colours’ of hydro-  and hydrocarbons. In fact, this hydrogen   chemicals, Government of India  5-tpa (tonnes per annum), is negligible  Concluding remarks  and investors, including the Bill Gates
 gen denotes the starting raw material  found underground, used to be consi-  Email: amiyakantidas2010@gmail.com  compared  to the current global grey   Hydrogen, especially  green hy-  ‘Breakthrough Energy  Ventures’ are
 and the process for its production.  dered problematic. In the last few years,   hydrogen production of 80-mtpa.   drogen, has emerged as a clean fuel  in the process of drilling test wells in
 Hydrogen is the most abundant chemical  however, attention  has been  drawn to  gists from the  University  of Lorraine   worldwide in the race  to curb carbon  Midwestern states of the US.
 element  in the universe, but found as  this geological resource. Some are call-  and of France’s National Centre of   Australia  emissions. But manufacturing it by
 compounds with other elements like in  ing this naturally occurring hydrogen  Scientifi c Research, hit a potential deposit   In November 2020, Luke Titus, an  electrolysis  of water and from other   Public sector companies in the oil &
 water and fossil fuels.  as ‘gold hydrogen’ as it was thought to  of naturally occurring hydrogen. Initial   Australian, was reading an obscure  non-fossil sources remains costly. Geo-  gas business have formed a ‘Hydrogen
 be too expensive. But recent assump-  estimates indicate that the sub-soil of   1944 report: Bulletin Number 22 from  logical hydrogen, on the other hand,  Corpus  Fund’  to  fi nance  R&D  activi-
 Grey hydrogen refers to hydrogen  tions point that it could be the cheapest  the region could be one of the biggest   the Department of Mines, of the Geo-  could be a low-cost form of energy,  ties on various facets of hydrogen. The
 produced by processing natural  gas.  source of clean hydrogen.   source of white hydrogen. Europe is   logical Survey  of  South  Australia. It  obtained through drilling techniques  ‘Hydrogen  Association  of India’, as
 Black hydrogen is produced from coal.   gripped by a gas supply crisis due to the   contained  an analysis of data from  long mastered in the oil & gas industry.  well as the above fund, should include
 While producing hydrogen from hydro-  Accidental discovery  Russia-Ukraine confl ict. The discovery   farmers who had banded together for  The presence of helium, a scarce resource  white hydrogen in their agenda on an
 carbons by steam reforming, carbon   In 1987, in the village of Bourake-  of  white  hydrogen hence  brought  a   oil, using divining rods and other ques-  material, is an added sweetener. The US  immediate basis.
 dioxide is produced as by-product. If this  bougou in Western Mali, a borehole was  wave of enthusiasm in energy circles.  tionable techniques. It showed the data
 carbon dioxide  is captured  and stored  being drilled to fi nd water, but even at   from one borehole, drilled in 1921 on   ABOUT THE AUTHOR
 or utilised, the hydrogen is termed blue  a depth of 108 metres it remained dry.   The team set out to make an esti-  Kangaroo Island, which produced as
 hydrogen. Green hydrogen comes from  Meanwhile,  ‘wind’  was  coming out  of  mate of the level and total quantity of   much  as 80%  hydrogen.  At  another   Mr. Amiya Kanti Das (born 1939) is a B.Sc (Hons.) and
 electrolysis  of water  using electricity  the hole. When one driller peered into  methane present in the sub-soil and to   well, on the nearby  Yorke Peninsula,   M.Sc in Chemistry from Calcutta University. After a stint in
 generated from renewable sources like  the hole while smoking a cigarette, the  see if the production  is commercially   it was  close to  70%.  Since February,   research on natural products, he was awarded C.Chem., MRSC
 solar, hydro or wind.  ‘wind’ exploded in his face. He did not  viable. Following  chemical monitor-  2021, South  Australia has started   from Royal Society of Chemistry, London. He is a member of
 die, but was burned. It took the crew  ing of the rock strata and accompany-  allowing drilling for hydrogen and   Indian Institute of Chemical Engineers and American Chemical
 What is white hydrogen?  weeks to snuff out the fi re and cap the  ing methane deposit, a high proportion   several enterprises are on the fray, apart   Society.
 White hydrogen is naturally-  well. The villagers shunned the site and  of hydrogen was detected. As the depth   from the company ‘Gold Hydrogen’
 occurring geological hydrogen found in  forgot it. Almost 20 years later, drillers  grew, the concentration of hydrogen   formed by Luke Titus.  He underwent specialised in-plant training in Germany and attended a course
 underground deposits. It is often found  on the hunt for fossil fuels confi rmed the  also grew, reaching 20% at 1,250-  of ‘Choice of Proper Technology’ in the University of Strathclyde, Glasgow and
 near tectonic  fault-lines  as the 1,200-  accidental discovery of naturally occur-  meter down. On the basis of acquired data   India  a course on ‘Project Appraisal’ in IIM, Bangalore. He has done Post Graduate
 mile long mid-continental rift running  ring hydrogen below hundreds of feet  and computer modelling, it has been   In India, the ONGC Research Cen-  Specialisation in Environmental Control, from University of Ghent, Belgium.
 through central US.  The  geological  of arid earth of West Africa in abundant  estimated that the Lorraine deposit   tre, the research wing of oil producer,
 survey of the US predicts its abundant  quantity.  Within few months a Ford  could possibly contain up to 46-mt of   ONGC,  informed that hydrogen has   Widely travelled in Europe and India, he was a regular contributor in chemi-
 presence.  engine tuned to burn hydrogen was hooked  white hydrogen.   been found in some wells dug for petro-  cal  journals  during  80’s  and  90’s  and  is  profi cient  in  German  and  Russian.
 up to a 30-kW (kiloWatt) generator, to   leum crude. But there is no programme   Before  retirement  on superannuation  on May 31, 1997 from the  post of
 How is it formed?  give the village the fi rst taste of electrical   France’s other potential white hydro-  yet  to  extract  this  hydrogen.  The   Industrial Advisor in the Dept. of Chemicals and Petrochemicals, he dealy with
 Unlike oil and gas deposits, which  benefi ts and remains the only place of  gen reserves currently explored are   Energy Research Institute, (TERI), a well-  diverse chemical industries for three decades.
 are unsustainable,  geological  hydro-  using white hydrogen till date.   in the  Alps, New Caledonia  and the   known think-tank on energy issues, has
 gen is believed to be generated conti-  Pyrenees.  Together with the Lorraine
 nuously. There are different theories as to  Global explorations  deposit,  these  reserves could  enable
 how it is produced. The most prevailing   France to produce 3-mt of white hydro-  Chemical Weekly | Import-Export Data | Market Surveys
 one is that it’s a product of a continuous  France  gen annually.  Directories | Business Forums | Expositions
 chemical reaction  between water and   At times one gets something not   The only organisation in India catering exclusively to the needs of the entire chemical industry
 iron rich minerals at high temperature  been sought, and on occasions this   Apart from these, other deposits
 and pressure.  discovery is more valuable  than one  have been discovered in Canada, the
 which was originally thought. Such an  Philippines,  Australia,  Brazil,  Oman,   Contact:
 The existence of hydrogen deep  incident  happened recently  in France.  Turkey and elsewhere in Europe in-  SEVAK PUBLICATIONS PVT. LTD.
 underground is no new revelation. It has  While probing the sub-soil in Lorraine,  cluding Spain, Germany, Kosovo, Ice-  602-B, Godrej Coliseum, K.J. Somaiya Hospital Road, Behind Everard Nagar, Sion (E), Mumbai 400 022.
 been known to geologists for decades.  South-eastern France, a team of geolo-  land, Finland, Sweden, Poland, Serbia,   Phone: +91-22-24044471 / 72;  Email: admin@chemicalweekly.com


 190  Chemical Weekly  October 24, 2023  Chemical Weekly  October 24, 2023                             191


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