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Special Report



       Explosions of small LPG cylinders and their prevention


       Background                          The government wants to make the   ASHOK GUPTA
          n India, “accidental” explosions of  lives of urban and rural poor house-  Email: k.ashok.g.@gmail.com
          small domestic liquefi ed petroleum  wives more comfortable  through its
       Igas (LPG) cylinders are frequently  Ujjawla scheme  of providing  LPG in   This author believes that most of
       reported. Most  of  these cause serious  every home. Many such homes are just  these “accidents”  can be, and must
       damage to property and many lives are  one room, including the kitchen, and often  be, prevented. It will save hundreds of
       lost. We refer to an answer(1) to a Rajya  have an inflammable thatched roof.  lives every year and prevent damages
       Sabha question about LPG-related  That may further increase the number  to properties running into hundreds of
       accidents by the Ministry of Petroleum &  of LPG cylinder explosions.  crores of rupees. As human lives are
       Natural  Gas  (MoPNG).  It gave  the                               priceless,  necessary safety measures
       fi gures for the years 2016-17 and 2018-19.  Purpose               may be formulated and implemented by
       Based on the figures quoted by      The purpose of this document is to  the concerned government authorities,
       MoPNG, we estimate approximate  look at the possible causes of frequent  as soon as possible.
       annual accidents in India at about 2,000  domestic LPG cylinder explosions and
       or about fi ve per day. The approximate  measures for the prevention of these  Science behind explosions
       compensation paid to victims of  explosions.                          Explosions are caused by the sudden
       domestic LPG explosion accidents was                               (within a few milliseconds) release of a
       Rs. 22-crore in 2016-17.            This author believes that India has  lot of energy. Some common types of
                                         ignored the following two standard  man-made explosions and their causes
          When considered on a per million  safety rules, which are globally fol-  are listed below. All the following four
       LPG users basis, the accidents, deaths  lowed for all pressurized liquid gas cy-  types of explosions lead to high-power
       and loss of property fi gures are dispro-  linders (including propane and LPG):  shockwaves, causing a loud sound and
       portionately  high in India compared   Prohibit storage and use of all such  severe damage  to surrounding struc-

       with other countries.               cylinders indoors; and         tures and people.
                                            Provide a Pressure Relief  Valve
          The explanation given for these   (PRV) to prevent the build-up of any   Explosions may be caused due to
       “accidents” is “LPG leakage as the pri-  dangerously high internal pressure.   excessive internal pressure inside a
       mary cause”. This has been the offi cial                           tank, like in the case of steam boilers.
       stand since the 1960s when LPG was   If India also follows these two  When the internal overpressure exceeds
       fi rst introduced in India as a clean and  basic safety rules for small LPG cylin-  the bursting pressure, the envelope
       convenient cooking fuel. However, this  ders, most of these “explosions” will  explodes violently. Remember that these
       author thinks otherwise.          be  eliminated.  Presently,  these  are  explosions are caused only by force
                                         kept indoors, usually under the kitchen  exerted by the internal pressure of the
          Let us consider the data(2) on home  platform. In case of any fi re inside the  fl uid  inside. This  mechanical  effect  is
       fi res  in  2017  in  India  as  given  by  the  kitchen  or indoors due to any reason,  independent  of  the  nature  of  the  fl uid
       Govt. of India. It shows that the  including any leakage of LPG, that may  inside.  Therefore, even water,  steam,
       total number of home fi res in 2017 was  heat the LPG cylinder. This will cause  air, and even any inert gas at any tem-
       7,660, killing 7,614 people. It implies  the LPG cylinder to explode, like an  perature but suffi ciently high pressure
       that  if one excludes the ~2,000 LPG  Improvised Explosive Device (IED).  will lead to this type of explosion and
       explosion-related  fi res  in  one  year,                          damage due to a catastrophic mechanical
       as  mentioned  in  the  fi rst  answer  by   At present more than 400-mn small  failure of the envelope.
       MoPNG,  approximately 5,660  home  LPG cylinders are in circulation. Most
       fi res  in  that  year  were  not  related  to  of these are kept and used in kitchens   Explosions may be caused due to
       LPG cylinder  explosions. Had there  or indoors in India. With nearly 8,000  a fast exothermic chemical chain reac-
       been any LPG cylinders in these ~5,660  home fi res reported every year in India,  tion; e.g., when an explosive mixture
       homes and if these were exposed to the  the potential danger of  LPG  cylinder  of any fuel and oxidizer  (air) is trig-
       heat  of  the  home  fi re,  many  of  those  explosions and resulting  loss of lives  gered by any spark or hot surface, as in
       cylinders may have also exploded.  and property is huge.           the case of gunpowder, TNT, or LPG.


       Chemical Weekly  May 7, 2024                                                                    167


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