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Special Report                                                                                                                                                                   Special Report


       larly  Type III and IV composites, are  industrial facilities, like refi neries. This  (LH ) or conversion to hydrogen carri-  will account for most of the low-carbon  small  form  factor,  and  high  power  have limitations, including the need for
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       popular for  fuel cell electric  vehicles  confi nement  emphasizes  the  pressing  ers like ammonia or LOHC. LH  ship-  hydrogen demand. Another promising  density,  coupled  with  quick  ramp-up  costly  platinum group  metal  catalysts
                                                                                                     2
       (FCEVs), with models like Hyundai’s  need  to  expand  pipeline  networks  to  ping  was  demonstrated  in  the  HESC   avenue is steelmaking, where hydrogen  times, mean that PEMFCs are particu-  and ultra-pure hydrogen to prevent cata-
       Nexo  and Toyota’s  Mirai  using Type  connect regions of production and con-  project by Kawasaki Heavy Industries’   can  produce  direct  reduced  iron  (DRI).  larly well suited to offer an alternative  lytic contamination. Consequently, alter-
       IV tanks at 700 bar. While compressed  sumption more widely, allowing future  Suiso  Frontier vessel, transporting   Major steelmaking companies view this  to  electrifi cation  in  the  zero-emission  native fuel cells like solid oxide fuel cells
       storage will remain dominant for light-  players to feed and draw H  from this  hydrogen from  Australia  to Japan.   as the  future of sustainable steel,  transportation sector.  (SOFCs) are gaining attention.
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       duty vehicles,  liquid hydrogen tanks,  network.  Pipelines  may  be  the  most  However, this pathway may be unviable   anticipating it to replace carbon-intensive
       with  their  larger  capacity,  are  being  cost-effective  solution for large-scale  compared  to hydrogen carriers  due to   blast furnace processes.  Additionally,   Fuel cell electric vehicles (FCEVs)   SOFCs’  high  operating  tempera-
       explored for heavy-duty sectors, as  and long-distance transport, so building  the diffi culties of dealing with LH .  hydrogen is seeing emerging industrial  are gaining traction worldwide, particu-  tures  allow  versatility  in  fuel  choice
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       seen with Daimler Truck.          networks is critical.                                                       uses in bio- and synfuel production, as  larly in Asia, with government targets  and eliminate the need for precious
                                                                             The advantage of using hydrogen         well as various power and heat appli-  and grants driving the development  metal catalysts. Their thermal exhaust
          Underground storage in reservoirs,   New  construction  is  planned,  with  carriers  is the utilisation  of existing   cations, including energy storage, com-  of  refuelling  infrastructure  and  new  can be harnessed for localized heating
       like salt caverns, is like traditional  projects like the HyNet  North  West  transport routes and vessels, albeit   bined heat & power (CHP) generation,  vehicle  concepts for light-, medium-  (CHP),  substantially  enhancing fuel
       natural gas storage. Companies like  Hydrogen  Pipeline  already  underway.  requiring additional processing facilities.   and heating across residential  and  and heavy-duty vehicles. The concept  cell effi ciency. However, these temper-
       Uniper and Gasunie aim to incor-  Repurposing natural gas pipelines is  Companies like Chiyoda Corporation    industrial  domains. Though  currently  of hub-to-hub routes is intriguing for  atures also cause thermal degradation
       porate these facilities into hydrogen  a possibility, but requires extensive  and  Hydrogenious  LOHC Techno-  minor contributors to hydrogen demand,  FCEVs, allowing for far greater range  and  lengthy  start-up/shut-down  times,
       pipelines soon.  They are anticipated  simulation,  testing, and risk evalua-  logies are commercializing their LOHC   these sectors are forecasted for consi-  than is possible for battery  electric  making SOFCs more suitable for con-
       to play a pivotal role in seasonal stor-  tion to identify suitable pipelines. The  solutions.  An ammonia receiving   derable long-term growth.  vehicles  (BEVs).  Fuel  cell  propulsion  tinuous  stationary  power  applications
       age, supplying the system during  European  Hydrogen  Backbone  initiative  terminal is also planned at the Port of                             systems are also eyed by long-haul  rather than rapid-start back-up power.
       demand  peaks. Underground facilities  is leading in terms of setting a vision  Rotterdam. Thus, many companies are   Hydrogen also offers an alternative  transport sectors, including marine,
       may also be used by industrial pro-  for a large-scale pipeline network, with  seeing ammonia and LOHCs as critical   means of power generation for several  rail, and aviation.     Despite the growth in the fuel cell
       jects as a buffer reserve of hydrogen –  over 30 operators participating – many  enablers of international  hydrogen   different  sectors, including  transpor-                   sector, it is worth tempering the hype.
       HYBRIT, a sustainable steelmaking  of the pipelines are planned to be repur-  supply chains. Hence, they are expected   tation,  back-up  power,  industry,  and   However, integrating fuel cell stacks  IDTechEx  forecasts  the  total  accumu-
       project  in  Sweden,  is  testing  such  a  posed  from  existing  networks.  Blend-  to play a substantial role in the future,   utilities.  Currently, proton exchange  with  appropriate  hydrogen  storage,  lative installations (in MW) of SOFCs
       concept using a lined rock cavern  ing hydrogen into natural gas is also a  considering  that  regions  like  Europe   membrane fuel cells (PEMFCs) are the  heat exchangers, and other balance of  to be an order of magnitude lower than
       (LRC). However, regulation and long  popular concept for partially decarboni-  and Japan may require net imports of   predominant choice for fuel cell instal-  plant components remains a challenge.  that  for  PEMFCs  solely  in  the  trans-
       project development times remain a  zing the heating and power sector, with  hydrogen.                        lations.  Low  operating  temperatures,  Despite  their  advantages,  PEMFCs  portation sector by 2033, while in turn
       key challenge for this storage type.  projects  like  HyDeploy  proving  blends
                                         of 20 vol% H  to be safe in existing  Hydrogen in action: End-use sectors &
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       Hydrogen distribution & its applica-  pipelines.  However,  higher  percent-  fuel cells
       tions                             age blends will require modifi cation of   Hydrogen  is  expected  to  signifi -
          Compressed and  liquid  hydrogen  many appliances and equipment in resi-  cantly  decarbonise  industries  where
       trailers  are currently used for small-  dential and industrial sectors.  it is traditionally employed,  such as
       scale  needs like refuelling  stations or                          refi ning, ammonia, and methanol pro-
       pilot projects.  While companies like   International  long-distance trans-  duction, by transitioning from grey to
       Hexagon Purus and Chart Industries  port may involve liquid hydrogen  blue and green hydrogen. These sectors
       have developed various types of com-
       pressed gas and liquid  transport ves-
       sels,  companies  like  LIFTE  H2  inno-
       vate with mobile refuelers to offset the
       scarcity of hydrogen refuelling stations.
       Such hybrid solutions will be needed in
       the future hydrogen energy system.

          There are about 5,000-km of hydro-
       gen pipelines globally, primarily  con-
       centrated  in areas like the Gulf Coast
       in  the  US  and  parts  of  Europe.  Man-
       aged by industrial  gas giants such as
       Air Products, Linde, and Air Liquide,
       they mainly supply hydrogen to nearby


       170                                                                   Chemical Weekly  February 6, 2024       Chemical Weekly  February 6, 2024                                                               171


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