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Special Report                                                                   Special Report



 Hydrogen’s decade ahead: Energising the future  ties. Consequently, governments are  energy  effi ciency  and  compatibility  solid  oxide  electrolyser  (SOEL),  uti-
       establishing  defi nitive  production  goals  with carbon capture technologies, crucial  lizing  a ceramic electrolyte,  and the
 ecarbonisation efforts  have   hydrogen  market  is  drawing  attention   CHINGIS IDRISSOV   for  upcoming  years.  For  instance,  the  for  cost-effi cient  blue  hydrogen  pro-  anion exchange  membrane electro-
 gained momentum globally in   from stakeholders globally.  Technology Analyst, IDTechEx  UK  targets  10-GW  of  low-carbon  duction.  Noteworthy  projects  utilising  lyser (AEMEL), which aims to merge
 Drecent years. Renewable energy,   hydrogen by 2030 (2.5-mtpa of blue H ,  ATR include  Air Products’ Net-Zero  the  advantages  of AWE  and  PEMEL.
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 electrifi cation,  and  battery  storage   A cohesive  value chain  is essen-  hydrogen originates from fossil fuel-  5-GW green H ),  while  the  US  aims  Hydrogen Energy Complex in Alberta  However,  IDTechEx  predicts  AWE
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 are primary solutions. However, some   tial  for realising hydrogen’s potential,  based grey and black  hydrogen, pro-  for 10-mtpa. Several other nations also  (Canada),  leveraging  Topsoe’s  Syn-  and  PEMEL  will  lead  the  market  in
 sectors remain diffi cult to decarbonize   encompassing  low-carbon  hydrogen  duced using steam methane reforming   have ambitious production objectives.  COR technology. IDTechEx anticipates  the coming decade due to their estab-
 using such methods, including  heavy   production, storage, and distribution  (SMR)  and  coal  gasifi cation.  These   However, the pace of new production  SMR, POX, and ATR to lead the blue  lished presence. Cutting  electrolyser
 industry, heating, and certain transport   infrastructure,  which  align  with  end-  methods signifi cantly contribute to CO 2   site project announcement and deve-  hydrogen sector in the coming decade,  plant costs (CAPEX/OPEX), operating
 sectors, such as aviation and shipping.   user demand. Analogous to the oil &  emissions. In response, numerous   lopment lags behind these targets due  with ATR  potentially  dominating  new  large-scale plants, and expanding
 Hydrogen offers a promising solution   gas sector, the  hydrogen value  chain  companies  are  pioneering  low-carbon   to the high costs of production (espe-  production capacity by 2034.  electrolyser  manufacturing  capacity is
 for these challenging sectors. Its poten-  comprises  upstream  (production),  hydrogen  production  techniques,  cially for green H ), lack of supporting   essential  for  the  future.  However,
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 tial as a fuel, energy carrier, and chemi-  midstream  (storage & transport), and  focusing on blue hydrogen (natural   renewable  and  CCUS  infrastructure,  Green hydrogen production tech-  access  to  affordable  renewable  electri-
 cal feedstock has led to many govern-  downstream (end-use) segments. Each  gas  reforming  with  CO  capture) or   long lead times to making fi nal invest-  nologies  city  will  ultimately  determine  green
 2
 ments formulating national hydrogen   segment poses unique technical  and  green  hydrogen  (water  electrolysis   ment  decisions,  as  well  as  challenges   Green hydrogen, produced through  hydrogen’s success.
 strategies. Consequently, companies   socio-economic challenges.  using renewable energy).  in  securing  fi nancing  and  permitting.  water  electrolysis  powered  by  renew-
 are seizing market opportunities, sup-  Coupled with an insuffi cient midstream  able  energy,  is  garnering  signifi cant  Hydrogen storage & its applications
 plying a range of services, products,   Hydrogen economy: Status vs ambition  The energy transition  necessi-  storage and distribution network, there  interest. Several technologies exist for   The  development  of  effi cient
 and technologies.  The burgeoning   Currently, over 98% of global  tates new low-carbon hydrogen facili-  is an immense opportunity for develop-  its production. The most established is  hydrogen transportation  and storage
       ment and innovation in both techno-  the alkaline water electrolyser (AWE),  is crucial to maximize  hydrogen’s
       logy and infrastructure across the value  which  uses  a  potassium  hydroxide  potential as an industrial feedstock, fuel,
       chain.                            (KOH)  alkaline  electrolyte.  Benefi t-  and energy carrier, acting  as a bridge
                                         ing from affordable construction  and  between  production  and  consumption.
       Blue hydrogen production technologies  catalytic materials like nickel and steel,  While  hydrogen boasts a high gravi-
          Currently, blue  hydrogen, derived  AWE boasts lower capital costs than its  metric  energy density, its  storage  and
       from natural gas, is the most cost-effec-  counterparts. Nonetheless, its dynamic  transport present challenges due to its
       tive  low-carbon  hydrogen  production  operability is poor, and its effi ciency is  low density at ambient conditions. To
       method, having an estimated levelized  low under atmospheric pressure. Hence,  improve its volumetric energy density,
       cost of hydrogen (LCOH) of around  pressurized AWEs have emerged on the  substantial compression (100-700 bar)
       US$2-4/kg  H . In comparison, green  market,  with  most  players  supplying  or  liquefaction at a  cryogenic -253°C
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       hydrogen  has a much  higher  LCOH  such systems.                  is  required.  However,  both  processes
       at  US$4-10/kg  H , depending  on the                              consume signifi cant energy, with com-
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       production method and regional fac-  The proton exchange  membrane  pression and liquefaction using 10-30%
       tors like renewable energy availability.  electrolyser (PEMEL) is the most popu-  and 30-40% of the  original  hydrogen
       Thus,  blue  hydrogen  is  viewed  as  a  lar technology,  as  it can integrate  energy, respectively.
       transitional solution until green hydro-  extremely  well  with  renewables  and
       gen becomes commercially viable.  follow their profi le, ramping production   Compressed gas and liquid hydro-
                                         up or down within minutes. This tech-  gen tanks are typically used for station-
          Several technologies can produce  nology has a different build and operat-  ary storage, like at refuelling stations.
       blue hydrogen.  The most prevalent is  ing principle to the AWE, using poly-  For  larger  storage  at  production  sites
       SMR. Other scalable  methods using  mer membranes, mainly Nafi on, as the  and terminals, liquid hydrogen spheres
       methane  have  emerged,  such as the  electrolyte. The downside is its depen-  are preferred.  Alternatives,  such as
       partial oxidation (POX) process, which  dency on platinum group metal (PGM)  metal  hydrides,  offer  lower  pressure
       transforms  waste  hydrocarbon  feed-  electrocatalysts, notably iridium oxide  operation (10-50 bar) and may be more
       stocks into valuable syngas and is used  at the anode – iridium is a costly and  suited for  energy  storage applications
       in some refi neries globally.      scarce mineral. Consequently, mini-  due to their effi ciency. However, these
                                         mizing PGM use and developing alter-  systems are  yet to be commercialized
          Another notable method is auto-  native catalysts is a key industry focus.  widely.
       thermal reforming (ATR), a hybrid of
       SMR and POX. ATR is favoured for its   Other technologies include the   Compressed hydrogen tanks, particu-


 168  Chemical Weekly  February 6, 2024  Chemical Weekly  February 6, 2024                             169


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