Page 189 - CW E-Magazine (12-12-2023)
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Special Report                                                                   Special Report



    Local-level public awareness train-  damage can progress much faster. Over  of diffi cult access. The safety of inspec-  tandem with  cathodic protection to   Popular coating materials used  ers and FBE with  heavy  duty impact
 ing, mock drills and audits.  the years, the corrosion eats away the  tors in examining these coupons is also   ensure the safety and economical  today include: liquid epoxy and fusion  resistance, cavitation  resistance, abra-
 thick wall and pipes can rupture, caus-  a critical issue. Probes used for measur-  operation of pipelines in the long run.  bonded  epoxy  (FBE);  polyolefi ns;  sion  protection and gouge protection.
 Detecting internal corrosion  ing gas leaks, fi re and explosion.  ing resistance suffer from similar limi-  polyesters; polypropylene (PP);  poly-  Dual-layer FBE coatings normally
 Corrosion of internal surfaces of a   tations.  Internal surface coatings also con-  ethylene (PE) and butyl rubber. Diffe-  have thicknesses varying from 550-850
 natural gas pipeline can be detected by  Monitoring techniques  tribute to the hydraulic fl ow effi ciency  rent nano-materials are also mixed with  microns, but for heavy duty piping, the
 many different techniques:  Detection  and monitoring  of gas  Non-intrusive techniques  of gas pipelines, along with the mitiga-  the resins to enhance the anti-corrosion  thickness may go up to 1,050 microns.
    Visual inspection of the inside  pipelines for internal corrosion is done   Ultrasonic devices  are the most   tion of metal loss due to corrosion.  properties.
 surface  of the  gas pipe  after  it is  by:  popular  non-intrusive systems. Pipe   Advanced plastic coatings used on the   The  three-layer  polyolefi n  FBE
 opened;     In-line detection techniques;  thickness is measured by applying a   internal surfaces of pipes ensure a lower   Today’s gas pipelines  are mostly  coatings can have a thickness ranging
    Measuring the wall thickness of the   Intrusive techniques;  voltage to the outer metallic surface of   surface roughness, as compared to the  coated with FBE. This coating requires  from 1,275-3,000 microns for moderate

 pipeline externally by using specifi c   Non-intrusive techniques; and  the pipe, across a piezo electric crystal,   surface of the metallic pipes they pro-  adequate surface preparation to ensure  to heavy duty applications. The system

 instruments;     Combination systems, comprising  generating  a sound wave in the ultra-  tect. Friction encountered by the fl ow-  strong long-term adhesion to the pipe  includes:  FBE bottom adhesion layer
    Critical  examination of installed   both intrusive  and non-intrusive  sonic band. The time required for travel   ing gas is reduced due to the coating,  surface. Key advantages of FBE coat-  (150 micron) with strong adhesion to
 corrosion coupons;  systems.  of the wave through the metal and back   and there are energy-savings in driving  ings  include: excellent physical pro-  the metallic substrate; a bonded poly-
    Examination of probes installed in   to the device is indicative of the pipe   gas compressors. When pipes are stored  perties,  such  as  fl exibility;  as  well  as  olefi n mid layer (12-150 micron) with
 the gas pipeline; and  In-line inspection  thickness. This method is safe for the   outside temporarily before installation,  resistance  to cavitation,  erosion, and  superior fl exibility; and a top PE or PP
    Using in-line monitoring or exami-  Inline  inspection involves smart  inspector, but it involves digging to get   an internal coating provides the neces-  slip. These coatings ensure superior  layer for  high-temperature and  mois-
 nation tools to inspect the pipe and  pigs, or sensing devices placed inside  access to the top surface of the pipe. It   sary temporary corrosion protection(5).  adhesion to steel surfaces even in hostile  ture-resistant applications. For  higher
 to mark the spots of metal wall loss,  gas pipelines at special  entry points.  may also fail to detect the onset of cor-  environments,  and can withstand heat  temperatures and offshore applications,
 pitting corrosion and rust formation.  These get carried by the gas fl ow along  rosion at an early stage.  Surface preparation  of up to 110°C.  PP is more appropriate. The high-den-
 a certain length of the pipe. If the pig-  The  longevity of  internal coating   sity  PE top  layer  provides  toughness
 Gas quality control  ging of the pipes at the time of initial  Combination techniques  of gas pipes depends on the quality of   FBE is available as a powder coat-  as  well as  reduced permeability for
 Risk of internal corrosion of the  construction is  not planned, it can   Some  companies offer  a combi-  surface preparation. Steps involved in  ing. It is charged electrostatically, to  oxygen and moisture.
 gas pipe is minimized by reducing the  require  costly  modifi cation  at  a  later  nation of an ultrasonic system and an   surface preparation include: chemical  enable it to attract and adhere to the
 contaminants  in the  gas entering  the  stage.  electrical resistance device. Others   (phosphoric acid) cleaning;  thermal  heated surface of the grounded metallic  Coextruded three-layer tapes
 inlet of the pipeline. Efforts are made to   use an instrument transducer, which is   cleaning;  internal grit blasting (which  pipe. The pipe is heated and maintained   Three-layer tapes  contain a  stabi-
 enforce strict quality control standards.   Certain sensors are able to measure  mounted permanently on  the pipeline   also reduces risk of stress corrosion  at 240°C, using induction heating  lized carrier fi lm of PE, covered with
 Gas  samples  are  analysed  on  fi xed  properties of pipeline contents indirectly  along with a handheld device carried by   cracking); and surface curing.  elements, ensuring that the powder has  an adhesive of a butyl-rubber material
 intervals, and solids and liquids taken  from the outside.  Acoustic emission  the inspector for recording the changes   enough time to melt, spread and cross-  on  the top and bottom of  the layers.
 from the inside of pipelines are also  techniques, for example, can measure a  in wall thickness  based on  transducer   During these steps, the removal of  link on the surface.  Adhesive layers, used in between the lay-
 checked for corrosive substances such  pipeline’s wall thickness from the out-  indication.  This system can be ope-  mill scale and other deposits from the   ers of three-layer coextruded tapes with
 as sulphur compounds and bacteria.  side.   rated by maintenance technicians   inside surface is ensured.  The most common gas pipeline  carrier  fi lms,  provide  seamless  adhe-
 checking the cathodic protection (CP)   coating systems are: Single FBE layer;  sion without any clearly marked inter-
 Monitoring natural  gas pipelines  Intrusive techniques  system, thus saving on the manpower   Selection of coating material  Dual FBE layer; and Three-layer sys-  face between the adhesive layer and the
 is both complicated as well as expen-  Intrusive techniques include corro-  required(4).  Factors to  be considered  during  tem (FBE with polyolefins or butyl  intermediate  carrier  fi lm.  These  tapes
 sive, because the pipelines are spread  sion coupons along the length of pipe-  the design and selection of coatings  rubber).  are wrapped in spirals inside and out-
 out through large areas. Sampling and  line; and probes that measure electrical   We  need to  progress toward real-  include(5):  side the pipe, forming a homogeneous
 investigation, as well as manual inspec-  resistance.  time monitoring, which is comprised of      Mechanical properties of  the coat-  FBE in single layer is coated with  seamless sleeve coating on the metal
 tion, costs billions of dollars per year.  permanently installed probes collecting   ing;  a thickness of 400-700 microns.  The  substrate. The layer of butyl rubber will
 The coupon is comprised of a strip  signals from continuously, and data-     Susceptibility  to damage during  application is solvent-free. It has inherent  self-amalgamate in  the  interface area,
 Moisture in the gas, and its ingress  of metallic substance having the same  logging devices that highlight changes   pipe  handling  for installation  and  chemical resistance,  but  cathodic dis-  producing an impermeable sealed pipe.
 at  pipe  joints,  greatly  infl uences  the  composition as the pipeline material.  in wall thickness and the rate of metal   repair;  bonding can occur in rare cases. FBE
 onset of corrosion. It dissolves sulphur  After its initial weight is recorded, the  loss(3, 4).     Soil chemistry;  is also highly compatible with cathodic  Some limitations of coating materials
 compounds and chlorine compounds. If  weight loss is monitored at a pre-     Compatibility for in-situ joint coat-  protection,  and has low permeability   Normally,  a  PE top  layer  restricts
 corrosion begins, on average  pipeline  determined interval by removing it and  Protective coatings  ing;   for oxygen.  the application to temperatures between
 thickness is reduced by almost 2 mils  accurately weighing it.  Weight loss   Along with cathodic protection, an      Pipeline operating conditions, such   -20°C and 80°C. On  the other hand,
 annually, but in many cases, corrosion  points to the onset of corrosion and its  anti-corrosion coating provides the best   as fl ow velocity, pressure changes,   Dual-layer  FBE is comprised of  the PP top layer makes it suitable for
 occurs much more rapidly. Moisture  progression. However, examination  is  practical  preventive measure against   temperature;   a  bottom anti-corrosion layer  of FBE  temperatures of up to 105°C. Specially
 can accumulate at bends, pipe joints  an important limitation in diffi cult ter-  explosions and corrosion damage. Both      Compatibility  with the cathodic  with strong adhesion, with a top layer  formulated, high-temperature single
 and low-lying zones, where corrosion  rains, as corrosion often occurs in spots  internal and external coatings work in   protection selected for the pipeline.  designed  and  formulated  with  fi ll-  and dual-layer FBE can be used up to


 188  Chemical Weekly  December 12, 2023  Chemical Weekly  December 12, 2023                           189


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