Page 168 - CW E-Magazine (15-10-2024)
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News from Abroad


       PREVENTING FIRES
       LG Chem finds solution to battery thermal runaway

       problem


          South  Korea’s  LG  Chem  said  it  has   Leading cause of electric vehicle   the batteries, all of the standard batteries
       developed a temperature-responsive Safety   battery fires          caught fire. In contrast, 70% of the bat-
       Reinforced Layer  (SRL),  a  material    Thermal runaway, a leading cause of  teries equipped with the thermal runaway
       designed to suppress thermal runaway. In  electric vehicle (EV) battery fires, occurs  suppression material did not ignite at all,
       collaboration with Prof. Lee Minah’s team  when the cathode and anode inside the bat-  while the remaining 30% saw flames, but
       from  the  Department  of  Battery  Engi-  tery unintentionally come into direct con-  they were extinguished within seconds.
       neering at Pohang University of Science  tact, causing a short circuit and generating
       and  Technology  (POSTECH),  a  private  heat. Within seconds, the temperature can   While  previous  methods  involved
       research  university  in  South  Korea,  the   rise to nearly 1,000°C, leading to a fire.  placing  temperature  –  responsive  mate-
       material was analysed, while safety verifi-  The thermal runaway suppression material  rials inside the battery cell, they often faced
       cation was conducted in partnership with  is expected to be effective in preventing   issues with slow reaction times or reduced
       LG Energy Solution. The research findings  fires  by  quickly  blocking  the  reaction   energy  density.  LG  Chem  said  it  has
       were  published  online  in  the  September  path at the early stages of overheating.  successfully  developed  a  material  that
       edition of Nature Communications, one of                           resolves  such  issues,  backed  by  their
       the world’s leading scientific journals.  In both battery impact and penetration  expertise  and  patented  material  design,
                                         tests, the batteries equipped with the ther-  allowing  for  rapid  application  in  mass
          The  thermal  runaway  suppression   mal runaway suppression material either  production processes.
       material  developed  by  LG  Chem  is  a   did  not  catch  fire  at  all  or  extinguished
       composite  that  changes  its  electrical   the  flames  shortly  after  they  appeared,   LG Chem has completed safety verifi-
       resistance based on temperature, acting as  preventing a full-blown thermal runaway  cation tests for the thermal runaway sup-
       a “fuse” that blocks the flow of electricity  event.               pression  material  in  mobile  batteries
       in the early stages of overheating.                                and  plans  to  continue  safety  testing  for
                                           In a penetration test involving mobile  large-capacity  EV  batteries  through  next
          The research team created this material  Lithium  Cobalt  Oxide  (LCO)  batteries,  year.
       in the form of a thin layer, just 1-μm thick,  where a nail was used to puncture the bat-
       positioned between the cathode layer and  tery, only 16% of regular batteries did not   Mr.  Lee  Jong-Ku,  CTO  of  LG
       the  current  collector  (an  aluminium  foil  catch fire. However, none of the batteries  Chem, stated, “This is a tangible research
       that acts as the electron pathway) in the  with  the  thermal  runaway  suppression   achievement that can be applied to mass
       battery.  When  the  battery’s  temperature  material experienced any fire incidents.  production in a short period of time. We
       rises  beyond  the  normal  range,  between                        will enhance safety technology to ensure
       90-130°C, the material reacts to the heat,   In  an  impact  test  on  Nickel  Cobalt  customers  can  use  EVs  with  confidence
       altering its molecular structure and effec-  Manganese  (NCM)  batteries  for  EVs,  and contribute to strengthening our com-
       tively suppressing the flow of current.  where a 10-kg weight was dropped onto  petitiveness in the battery market.”
          This  thermal  runaway  suppression  Mitsui Chemicals’ arm resumes ethylene

       material is highly responsive to tempera-  cracker operations
       ture, with its electrical resistance increasing
       by 5,000 ohms (Ω) for every 1°C rise in   Japan’s  Mitsui  Chemicals  has   plant  while  production  was  paused
       temperature.  The  material’s  maximum   announced  that  its  wholly-owned  for  scheduled  maintenance.  The
       resistance is over 1,000 times higher than  subsidiary,   Osaka   Petrochemical   restart  of  production  operations  was
       at  normal  temperatures,  and  it  also  fea-  Industries Ltd. has resumed operations  put off to resolve the problem. “After
       tures reversibility, meaning the resistance   at its ethylene plant. In August this year,  making  every  effort  to  restart  opera
       decreases and returns to its original state,  Osaka  Petrochemical  had  informed  tions  as  soon  as  possible,  the  plant
       allowing  the  current  to  flow  normally  about the discovery of a failure in the  resumed  operations  on  September
       again once the temperature drops.  steam  supply  system  at  the  ethylene  30,” the company said.


       168                                                                   Chemical Weekly  October 15, 2024


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