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Special Report                                                                   Special Report


 According to Mr. P.N. Rao,  Vice  climate change is changing traditional  improvement over the existing process   technologies  for producing Pharma
 President, GHCL Ltd., a leading soda  rainfall patterns.   from alum-treated brine. More particu-  grade salt meeting international specifi -
 ash producer, the alkali industry today   larly, it rectifi es the ratio of Ca to Mg   cations, as well as low-sodium salt of
 needs 99.60% min purity of salt, with   According to Dr. Kumar, thanks to  from a value of <1 to the range of 2-3,   botanical origin suitable for hyperten-
 0.05% max Ca, 0.03% max  Mg and  the development work done at CSIR-  which is desired by the alkali industry.   sive individuals advised low-salt diets.
 0.10% max of insolubles.   CSMCRI, it is now possible to produce  The technology has been transferred
 salt with a purity of 99.58% directly  several alkali producers.   Pharma grade salt has many appli-
 With the Kutch district accounting  in salt  works, as well  as grades suit-  cations, including for haemodialysis,
 for about half of Gujarat’s output, this  able  for membrane cell  operations (at  Speciality salts  making oral rehydration salts, osmotic
 can be a vulnerability in a world where  caustic  soda plants).  The latter is an   CSIR-CSMCRI has also developed   agents, and dietary formulations.  The
       process developed at CSIR-CSMCRI is
 Single-stage seawater desalination – a challenge   a combination of physical and chemi-
       cal treatments to remove the impuri-
 that still needs to be tackled  ties, and does not use barium chloride,   Mr. P.N. Rao  Dr. Arvind Kumar
       which is toxic in nature. According to
       a  technology compendium released  India (FSSAI) have been completed  tion), activated carbon & water, using
 Speaking to Chemical Weekly, Dr.  the  present  work is focused on over-  search Institute (CSIR-CGCRI)  to   by the laboratory, the process can be  and, once approved, the technology will  spent wash as the resource.
 Srinivasan noted that one of the areas  coming the  engineering challenges in  utilize the magnesium compounds for   scaled up to operate in a continuous  be available for licensing.
 where signifi cant social impact can be  module making,” he noted.  making refractories.  manner without the necessity of time-  The technology has been licensed
 made  is the development  of single-  consuming recrystallisation step.  Fertilisers from wastes  to  DCM Shriram Bio Enchem Ltd.,
 stage membranes for desalination of  Seawater magnesia  Marine polymers  CSIR-CSMCRI has also developed  which has constructed a plant in Hardoi
 seawater to  produce potable water.   Another area where the laboratory is   Marine polymers derived from   “Double fortifi ed salt – containing  technology for utilizing  sugarcane  district, Uttar Pradesh.
 This is currently largely the domain  focusing its expertise is in the purifi ca-  seaweeds can be an alternative to   iron and iodine – based on our techno-  molasses-based distillery spent wash for
 of three companies – two in the US  tion of seawater magnesia, the national  petroleum-derived polymers, particu-  logy will soon be available in the market,”  the production of 100% soluble fertili-  Technology to produce SoP (and
 and one in Japan – and all the mem-  requirements of which are currently fully  larly for making thin fi lms for packag-  Dr. Kumar added.  Testing studies for  ser grade sulphate of potash (SoP). The  magnesia)  from sea bittern  has been
 branes and modules used in India for  met through imports. The technical chal-  ing. The laboratory has been working   obtaining  certifi cation  from  the  Food  process involves recovery of potash,  licensed to  Tata  Chemicals Ltd.  and
 seawater desalination are imported  lenges stem from the fact that the mag-  with a leading multinational company   Safety and Standards  Authority of  organics (binder in cattle feed formula-  Archaen Chemical Industries Ltd.
 from one or the other.  nesia has a high boron content, which  for taking these polymers to the mar-
 is not acceptable for many applications.  ket, but performance failure in the in-
 “We have achieved comparable  The laboratory is also partnering with  tended application remains a problem   Marine organics from seaweeds
 performance of our membranes, and  CSIR-Central Glass and Ceramics Re-  that has not yet been fully resolved.
          Seaweed cultivation is a form of agricul-  management, as  biostimulants, and  as  weed polysaccharides like agar, carra-
       ture that can be remunerative, eco-friendly,  antibacterial agents, among others.  geenan and alginates, are biologically
       sustainable and expansive in scope. CSIR-                          tuneable, biocompatible and biode-
       CSMCRI has played a pioneering role in   According to Dr. Kamalesh Prasad,  gradable. Though small quantities are
       the commercial cultivation of seaweeds in  Chief Scientist, CSIR-CSMCRI, sea-  produced in India, most of the domes-
       India and more than 800 self-help groups                           tic demand (>80%) is met through im-
       in  Tamil Nadu, for instance,  earn their                          ports. “Lack of quality raw materials,
       livelihood from this activity.                                     focus on one product, poor technology
                                                                          choices leading to poor yields, and
          Seaweeds contain pigments, lipids,                              large  effl uent  generation  with  high
       proteins, polysaccharides, vitamins,                               BOD/COD are some of the challenges
       minerals and other bioactives. Extrac-                             producers face,” he noted.
       tion of marine organics with water has
       challenges and neoteric solvents like                                 Agarose, to cite one example, is
       Ionic liquids (ILs) and Deep Eutectic                              a heteropolysaccharide, generally ex-
       Solvents  (DES) (which  are  easier to                             tracted from certain red algae. It is
       easier to prepare than IL), have been                              one  of the two principal components
       developed at the laboratory.                                       of agar,  and  is  purifi ed  from  agar  by
                                                                          removing agar’s other component,
          Applications  of these organics  in-                            agaropectin.  Agarose is frequently
       clude as feed additive, in water quality   Dr. Kamalesh Prasad     used in molecular biology for the

 174  Chemical Weekly  August 20, 2024  Chemical Weekly  August 20, 2024                               175


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