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Special Report                                                                   Special Report



       Bio-based and biodegradable plastics industries

 Consumer  in China
 Biodiesel  Byproduct  Glycerol  Lactic  Polylactic  product
 acid
 acid
 (eg bioplastic cup)
       Executive summary                 from Chinese entrepreneurs acquired   ANN ZHANG
             hina has emerged as a global  through in-depth face-to-face inter-  nova-Institute
             leader in strategic technologies  views.                      Senior Industry Expert
 Fig. 1: Route from biomass to glycerol to lactic acid to end product.  Csuch as 5G, renewable energy,
 depending  on  the  specifi cations.  As   Electrons  and electric vehicles in the past two   Meanwhile, we would like to point   MICHAEL CARUS
 mentioned, one of the main challenges   decades.  This dominance may leave  out that the terms “bio-based  plastics”   Founder and CEO,
 is  the  diffi culty  of  processing  lignocellu-  European companies impressed and  and “biodegradable plastics” belong to   nova-Institute and Executive Manager
 lose and specifi cally separating out lig-  concerned  about competition  while  different  classifi cations.  According  to   Renewable Carbon Initiative (RCI)
 nin  from  cellulose.  The  effi cient  pre-  also sparking curiosity about China’s  Chinese national standard (GB/T 39514-
 treatment  of  lignocellulosic biomass   Chemicals  leapfrogging advancement in these  2020 and GB/T 20197- 2006), the “bio-  In  2022,  global plastics  pro-
 will present an important breakthrough.  Hydrogen  areas.  based plastics” refers to the plastics  duction reached 400.3-mt, with a
                                         (wholly or partly) derived from biomass  worldwide market value of US$712-
 Emerging routes from biomass to   Paving the way to a net-zero chemi-  feedstocks, and they are not necessa-  bn, an increase of about 1.6% from
 chemicals  cal industry in 2060, using renewable  rily degradable; while “biodegradable  2021.  Asia is the world’s largest
 Biomass and  bio-derived  products   biomass to produce bio-based chemi-  plastics” pertains to plastics that bio-  region for plastics production, with
 present a valuable opportunity to be   cals has been one of the promising  degrade by microorganisms under certain  a share of around 55%, of which
 electrocatalytically  converted into be-  transitional solutions for  the global  condition at the end of their life. “Bio-  China accounts for 32%, with 128-mt
 spoke chemicals, such as for cosmetics   Biomass  Water  chemical industry.  As China and  degradable plastics” may be made from  in 2022.
 and pharmaceuticals  – though, again,   Anode  Cathode  Europe strive to follow this path, a similar  bio-based or fossil feedstock. This report
 these  are  not  at  a  signifi cant  scale  of   question may exist within the European  outlines the characteristics of polybuty-  Projected 49% CAGR growth of
 production to substantially reduce   Fig. 2: Concept of a biomass electrolyser with high value chemicals and green hydrogen coproduction.  chemical  industry:  What  is  the  status  lene adipate terephthalate (PBAT), a bio-  bio-based plastics market in China
 chemical sector emissions in line with  to primary chemical markets. Lactic  place at much lower potentials com-  of the bio-based industry in China?  degradable plastic derived from fossil  by 2026
 net zero targets.  An example  of an  acid can be obtained directly  via the  pared to oxidation of water, the total   Can China and Europe fi nd a coopera-  resources. It also describes the proper-  China’s bio-based plastics industry
 alternative plastic production route and  fermentation of sugars present in bio-  electricity  input  required  is  signifi -  tive and win-win way to develop this  ties of polylactic acid (PLA) and poly-  is experiencing  rapid growth despite
 an example of potential green hydrogen  mass. However, recent studies suggest  cantly lower, reducing costs for hydro-  industry?   hydroxyalkanoates (PHAs), which are  being  in its  early stages, largely  pro-
 co-production is outlined in Figure 1.  that an electrochemical  and chemical  gen production.  bio-based and biodegradable, and poly-  pelled by policy incentives. Projections
 route might have both environmental   This report presents a timely mar-  amide (PA), which is bio-based, but not  suggest that  the industry  will  expand
 Glycerol to lactic acid  and technoeconomic advantages.  The key to realising this technology   ket analysis of China’s bio-based and  biodegradable.   substantially, reaching 2.53-mt by
 In  2022,  around  2.3  billion  litres   is developing cost-effective  catalysts   biodegradable plastics industry and   2026, up from 765,631-tonnes in 2023,
 of biodiesel were produced in the UK.  Co-producing green hydrogen and   that can achieve biomass partial oxida-  markets in 2024. Since this is nova-ins-  China: The world’s largest plastics   representing a notable CAGR of
 Glycerol is the main by-product of  chemicals from biomass  tion with high activity and high selec-  titute’s  fi rst  overview  of  the  Chinese  producer  approximately 49%.
 biodiesel production. Glycerol of high   An advantage of the electrocatalytic  tivity. The scale of possible hydrogen   market, the report may cover only key
 purity (>98%) can be electrocatalytically  processes described above is that these  production  is restricted  as the hydro-  products that dominate the Chinese
 converted to high value products, such  take place in electrolysers, identical to  gen extraction rate is around 10% of   market. However, it explores key mar-
 as organic acids, depending on the  water electrolysis – a well-established  the weight of the total biomass, though   ket  trends, policy dynamics, techno-
 catalyst and the potentials applied. The  technology used in, for example,  it could be used to feed back into the   logical advancements, major market
 selectivity to such products is diffi cult  hydrogen production. Instead of oxidising  chemical industry at the point of pro-  players, and growth opportunities. The
 to control and so is the separation of  water to create oxygen at the anode, a  duction for further use.  aim is to provide European chemical
 such mixtures from the aqueous phase.  bio-derivative  is oxidised to produce   companies with actionable insights to
 high value chemicals,  such as 5-(hy-  [Part 3, which will be published in the   navigate the Chinese market effectively,
 An alternative  route  to glycerol  droxymethyl) furfural (5-HMF) and   June 18 issue of  Chemical Weekly, will   enabling informed decisions about
 conversion comprises a mix of electro-  2,5-Furandicarboxylic acid (FDCA). At   focus on use as plastic  waste and carbon   market expansion or potential partner-
 catalytic and chemical routes, yielding  the cathode, green hydrogen is simul-  dioxide as feedstock]  ships in China. Notably, the report elu-
 lactic acid – a precursor to a bioderived  taneously produced from the protons   cidates all relevant critical policies in
 polymer – with high selectivity above  contained in biomass (Figure 2).  [The complete report, including refer-  the bio-based and biodegradable plas-
 85%.  Whilst the lactic  acid market  is   ences, can be viewed online at: www.royal-  tics markets since 2020. Furthermore,
 growing, this is not large in comparison   Since biomass oxidation takes   society.org/defossilising-chemicals]  it  provides  fi rsthand  market  insights


 188  Chemical Weekly  June 11, 2024  Chemical Weekly  June 11, 2024                                   189


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