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Special Report                                                                                                                                                                   Special Report



                                                                                                                     Bio-based and biodegradable plastics industries

                                                                                          Consumer                   in China
             Biodiesel     Byproduct        Glycerol        Lactic        Polylactic       product
                                                             acid
                                                                            acid
                                                                                       (eg bioplastic cup)
                                                                                                                     Executive summary                 from Chinese entrepreneurs acquired   ANN ZHANG
                                                                                                                           hina has emerged as a global  through in-depth face-to-face inter-  nova-Institute
                                                                                                                           leader in strategic technologies  views.                       Senior Industry Expert
                                 Fig. 1: Route from biomass to glycerol to lactic acid to end product.               Csuch as 5G, renewable energy,
       depending  on  the  specifi cations.  As                       Electrons                                       and electric vehicles in the past two   Meanwhile, we would like to point   MICHAEL CARUS
       mentioned, one of the main challenges                                                                         decades.  This dominance may leave  out that the  terms “bio-based plastics”   Founder and CEO,
       is  the  diffi culty  of  processing  lignocellu-                                                              European companies impressed and  and “biodegradable plastics” belong to   nova-Institute and Executive Manager
       lose and specifi cally separating out lig-                                                                     concerned  about competition  while  different  classifi cations.  According  to   Renewable Carbon Initiative (RCI)
       nin  from  cellulose.  The  effi cient  pre-                                                                   also sparking curiosity about China’s  Chinese national standard (GB/T 39514-
       treatment  of  lignocellulosic biomass        Chemicals                                                       leapfrogging advancement in these  2020 and GB/T 20197- 2006), the “bio-  In  2022,  global plastics  pro-
       will present an important breakthrough.                                       Hydrogen                        areas.                            based plastics” refers to the plastics  duction reached 400.3-mt, with a
                                                                                                                                                       (wholly or partly) derived from biomass  worldwide market value of US$712-
       Emerging routes from biomass to                                                                                  Paving the way to a net-zero chemi-  feedstocks, and they are not necessa-  bn, an increase of about 1.6% from
       chemicals                                                                                                     cal industry in 2060, using renewable  rily degradable; while “biodegradable  2021.  Asia is the world’s largest
          Biomass and  bio-derived  products                                                                         biomass to produce bio-based chemi-  plastics” pertains to plastics that bio-  region for plastics production, with
       present a valuable opportunity to  be                                                                         cals has been one of the promising  degrade by microorganisms under certain  a share of around 55%, of which
       electrocatalytically  converted into be-                                                                      transitional solutions for  the global  condition at the end of their life. “Bio-  China accounts for 32%, with 128-mt
       spoke chemicals, such as for cosmetics        Biomass                          Water                          chemical industry.  As China and  degradable plastics” may be made from  in 2022.
       and pharmaceuticals  – though, again,   Anode                                             Cathode             Europe strive to follow this path, a similar  bio-based or fossil feedstock. This report
       these  are  not  at  a  signifi cant  scale  of                                                                question may exist within the European  outlines the characteristics of polybuty-  Projected 49% CAGR growth of
       production to substantially reduce   Fig. 2: Concept of a biomass electrolyser with high value chemicals and green hydrogen coproduction.  chemical  industry:  What  is  the  status  lene adipate terephthalate (PBAT), a bio-  bio-based plastics market in China
       chemical sector emissions in line with  to primary chemical markets. Lactic  place at much lower potentials com-  of the bio-based industry in China?  degradable plastic derived from fossil  by 2026
       net zero targets.  An example  of an  acid can be obtained directly  via the  pared to oxidation of water, the total   Can China and Europe fi nd a coopera-  resources. It also describes the proper-  China’s bio-based plastics industry
       alternative plastic production route and  fermentation of sugars present in bio-  electricity  input  required  is  signifi -  tive and win-win way to develop this  ties of polylactic acid (PLA) and poly-  is experiencing  rapid growth despite
       an example of potential green hydrogen  mass. However, recent studies suggest  cantly lower, reducing costs for hydro-  industry?               hydroxyalkanoates (PHAs), which are  being  in its  early stages, largely  pro-
       co-production is outlined in Figure 1.  that an electrochemical  and chemical  gen production.                                                  bio-based and biodegradable, and poly-  pelled by policy incentives. Projections
                                         route might have both environmental                                            This report presents a timely mar-  amide (PA), which is bio-based, but not  suggest that  the industry  will  expand
       Glycerol to lactic acid           and technoeconomic advantages.      The key to realising this technology    ket analysis of China’s bio-based and  biodegradable.               substantially, reaching 2.53-mt by
          In  2022,  around  2.3  billion  litres                         is developing cost-effective  catalysts    biodegradable plastics industry and                                 2026, up from 765,631-tonnes in 2023,
       of biodiesel were produced in the UK.  Co-producing green hydrogen and   that can achieve biomass partial oxida-  markets in 2024. Since this is nova-ins-  China: The world’s largest plastics   representing a notable CAGR of
       Glycerol is the main by-product of  chemicals from biomass         tion with high activity and high selec-    titute’s  fi rst  overview  of  the  Chinese  producer               approximately 49%.
       biodiesel production. Glycerol of high   An advantage of the electrocatalytic  tivity. The scale of possible hydrogen   market, the report may cover only key
       purity (>98%) can be electrocatalytically  processes described above is that these  production  is restricted  as the hydro-  products that dominate the Chinese
       converted to high value products, such  take place in electrolysers, identical to  gen extraction rate is around 10% of   market. However, it explores key mar-
       as organic acids, depending on the  water electrolysis – a well-established  the weight of the total biomass, though   ket  trends, policy dynamics, techno-
       catalyst and the potentials applied. The  technology used in, for example,  it could be used to feed back into the   logical advancements, major market
       selectivity to such products is diffi cult  hydrogen production. Instead of oxidising  chemical industry at the point of pro-  players, and growth opportunities. The
       to control and so is the separation of  water to create oxygen at the anode, a  duction for further use.      aim is to provide European chemical
       such mixtures from the aqueous phase.  bio-derivative  is oxidised to produce                                 companies with actionable insights to
                                         high value chemicals,  such as 5-(hy-  [Part 3, which will be published in the   navigate the Chinese market effectively,
          An alternative  route  to glycerol  droxymethyl) furfural (5-HMF) and   June 18 issue of  Chemical Weekly, will   enabling informed decisions about
       conversion comprises a mix of electro-  2,5-Furandicarboxylic acid (FDCA). At   focus on use as plastic  waste and carbon   market expansion or potential partner-
       catalytic and chemical routes, yielding  the cathode, green hydrogen is simul-  dioxide as feedstock]         ships in China. Notably, the report elu-
       lactic acid – a precursor to a bioderived  taneously produced from the protons                                cidates all relevant critical policies in
       polymer – with high selectivity above  contained in biomass (Figure 2).  [The complete report, including refer-  the bio-based and biodegradable plas-
       85%.  Whilst the lactic  acid market  is                           ences, can be viewed online at: www.royal-  tics markets since 2020. Furthermore,
       growing, this is not large in comparison   Since biomass oxidation takes   society.org/defossilising-chemicals]  it  provides  fi rsthand  market  insights


       188                                                                     Chemical Weekly  June 11, 2024        Chemical Weekly  June 11, 2024                                                                  189


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